Evidence of a higher-order singularity in dense short-ranged attractive colloids.
نویسندگان
چکیده
We study a model in which particles interact through a hard-core repulsion complemented by a short-ranged attractive potential of the kind found in colloidal suspensions. Combining theoretical and numerical work we locate the line of higher-order glass-transition singularities and its end point-named A4-on the fluid-glass line. Close to the A4 point, we detect logarithmic decay of density correlations and a sublinear power-law increase of the mean square displacement, for time intervals up to 4 orders of magnitude. We establish the presence of the A4 singularity by studying how the range of the potential affects the time window where anomalous dynamics is observed.
منابع مشابه
Activated bond-breaking processes preempt the observation of a sharp glass-glass transition in dense short-ranged attractive colloids.
We study-using molecular dynamics simulations-the temperature dependence of the dynamics in a dense short-ranged attractive colloidal glass to find evidence of the kinetic glass-glass transition predicted by the ideal mode coupling theory. According to the theory, the two distinct glasses are stabilized, one by excluded volume and the other by short-ranged attractive interactions. By studying t...
متن کاملConfirmation of anomalous dynamical arrest in attractive colloids: a molecular dynamics study.
Previous theoretical simulation and experimental studies have indicated that particles with a short-ranged attraction exhibit a range of dynamical arrest phenomena. These include very pronounced reentrance in the dynamical arrest curve, a logarithmic singularity in the density correlation functions, and the existence of "attractive" and "repulsive" glasses. Here we carry out extensive molecular...
متن کاملDynamical arrest in attractive colloids: the effect of long-range repulsion.
We study gelation in suspensions of model colloidal particles with short-ranged attractive and long-ranged repulsive interactions by means of three-dimensional fluorescence confocal microscopy. At low packing fractions, particles form stable equilibrium clusters. Upon increasing the packing fraction the clusters grow in size and become increasingly anisotropic until finally associating into a f...
متن کاملCrystallization and gelation in colloidal systems with short-ranged attractive interactions.
We systematically study the relationship between equilibrium and nonequilibrium phase diagrams of a system of short-ranged attractive colloids. Using Monte Carlo and Brownian dynamics simulations we find a window of enhanced crystallization that is limited at high interaction strength by a slowing down of the dynamics and at low interaction strength by the high nucleation barrier. We find that ...
متن کاملNumerical study of the glass-glass transition in short-ranged attractive colloids
We report extensive numerical simulations in the glass region for a simple model of short-ranged attractive colloids, the square well model. We investigate the behavior of the density autocorrelation function and of the static structure factor in the region of temperatures and packing fractions where a glass-glass transition is expected according to theoretical predictions. We strengthen our ob...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Physical review letters
دوره 91 26 Pt 1 شماره
صفحات -
تاریخ انتشار 2003